Запис Детальніше

The influence of pressure and dissolved gases in petroleum on the efficiency of wax deposition inhibitors

Електронний науковий архів Науково-технічної бібліотеки Національного університету "Львівська політехніка"

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Title The influence of pressure and dissolved gases in petroleum on the efficiency of wax deposition inhibitors
Вплив тиску і розчинених у нафті газів на ефективність інгібіторів парафінових відкладів
 
Creator Vieira, Lenise
Buchuid, Maria
Lucas, Elizabete
 
Subject high pressure mDSC
viscosity
crude oil
paraffin
wax crystallization
deposition inhibitors
 
Description Evaluations of wax inhibitors carried out in laboratories are generally performed on stabilized oil samples, that is, without the presence of natural gas and at atmospheric pressure. Therefore, the effects of two important factors that influence wax solubility – the light fractions and temperature – are not considered, and the
results may not reflect what really happens in production
lines and facilities. This work evaluates the efficiency of
two wax inhibitors based on ethylene copolymer and vinyl
acetate, at four concentrations, in a sample of paraffin oil
in the presence of light fractions and under pressure. The
parameter employed in the evaluation was the wax
appearance temperature (WAT), or the cloud point, determined by high-pressure differential scanning calorimetry. The gas used was a mixture of eight
components and the tests were run at three pressures. In
general, the inhibitors had little influence on the cloud point
and a pronounced effect on the pour point and viscosity.
In this case it was possible to observe changes in the WAT with both wax inhibitors in the tests conducted at atmospheric pressure up to 150 bar and in the presence of the multi-component gas mixture, suggesting that one of the mechanisms through which wax deposition inhibitors work is polynucleation.
 
Date 2009-09-14T08:39:28Z
2009-09-14T08:39:28Z
2008
 
Type Article
 
Identifier Vieira, L. The influence of pressure and dissolved gases in petroleum on the efficiency of wax deposition inhibitors / Lenise Vieira, Maria Buchuid, Elizabete Lucas // Chemistry & Chemical Technology. – 2008. – Volume 2, number 3. – P. 211–215. – Bibliography: 11 titles.
http://ena.lp.edu.ua:8080/handle/ntb/1559
 
Publisher Publishing House of Lviv Polytechnic National University