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Structural Evolution and Phase Transformation in Nanoquasicrystalline Al-Fe-Cr Alloy: DSC Analysis

Electronic Archive of Sumy State University

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Title Structural Evolution and Phase Transformation in Nanoquasicrystalline Al-Fe-Cr Alloy: DSC Analysis
 
Creator Byakova, A.V.
Cherednichenko, V.V.
Scheretskiy, A.A.
Vlasov, A.A.
Yurkova, A.I.
 
Subject Nanoquasicrystals
Al-Fe-Cr Based Alloy
Structural Evolution
Phase Transformation
 
Description Kinetic parameters for microstructural evolution and phase transformation in water atomized Al-Fe-Cr
based alloy with nominal composition Al94Fe3Cr3 have been examined by means of developed precise method
of DSC technique and confirmed by the results of XRD analysis. Two exothermic reactions including that
with a maximum at 380 – 400 degrees Celsius has been ascribed to dislocation reorganisation and recrystallisation process within the Al matrix although the main exothermic reaction with a maximum around 540 degrees Celsius arose
from decomposition of icosahedral quasicrystalline particles and simultaneous formation of the metastable
Al6Fe phase and more stable crystalline particles compositionally corresponded to the O-Al13Cr2 and
O-Al13Fe4 phases. Activation energy for the main exothermic reaction has been found to be roughly
about 53.1 kJ mol-1 which is significantly smaller than that for the bulk diffusion of either iron or chromium atoms in aluminium and very close to that for the vacancy migration.
 
Publisher Sumy State University
 
Date 2014-05-23T05:30:16Z
2014-05-23T05:30:16Z
2012
 
Type Article
 
Identifier Structural Evolution and Phase Transformation in Nanoquasicrystalline Al-Fe-Cr Alloy: DSC Analysis [Текст] / A.V. Byakova, V.V. Cherednichenko, A.A. Scheretskiy et al. // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V.1, No1. - 01PCN19
http://essuir.sumdu.edu.ua/handle/123456789/34854
 
Language en