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The Influence of Annealing Thermal on the Properties of Au:TiO2 Nanocomposite Film

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Title The Influence of Annealing Thermal on the Properties of Au:TiO2 Nanocomposite Film
 
Creator Marin, A.A.
Moura, С.
Munteanu, D.
 
Subject Thin films
Gold
Sputtering
Surface plasmon resonance
 
Description Two sets of nanocomposite films consisting of different atomic concentrations of Au dispersed in a TiO2
dielectric matrix were deposited by DC reactive magnetron sputtering, and subjected to several annealing
trataments in vacuum, for temperatures ranging from 300 to 800 0C. The obtained results show that the
structure and the size of Au clusters, together with the matrix crystallinity, changed as a result of the annealing
As a result of these structural variations the film optical properties were modified too. The optical
changes, and the correspondent Surface Plasmon Resonance effect were confirmed by reflectivity and
CIELab colour measurements. XRD analysis confirmed the presence of gold in all the samples, and the
crystallization of the TiO2 matrix for the samples annealed at temperatures above 4000C. With further increase
of the annealing temperature, there is a change from the TiO2 anatase phase into rutile-type structure.
Simultaneously, the Au atoms are organized in crystalline nanoparticles (revealing an fcc-type structure,
with the (111) preferential growth orientation).
 
Publisher Sumy State University
 
Date 2014-05-23T10:35:24Z
2014-05-23T10:35:24Z
2012
 
Type Article
 
Identifier Marin, A. A. The Influence of Annealing Thermal on the Properties of Au:TiO2 Nanocomposite Film / A. A. Marin, C. Moura, D. Munteanu // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No2. - 02NFC25-02NFC25
http://essuir.sumdu.edu.ua/handle/123456789/34916
 
Language en