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Platinum Nanoparticles Supported on Reduced Graphite Oxide as Hydrogenation Catalyst

Electronic Archive of Sumy State University

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Title Platinum Nanoparticles Supported on Reduced Graphite Oxide as Hydrogenation Catalyst
 
Creator Kushch, S.D.
Kuyunko, N.S.
Muradyan, V.E.
Korshunova, L.A.
Dremova, N.N.
Tarasov, B.P.
 
Subject Graphite oxide
Platinum nanoparticles
Catalyst
Hydrogenation
 
Description Platinum nanoparticles supported on reduced graphite oxide are produced by reduction of a slurry including graphite oxide and H2PtCl6·xH2O, and pyridine as modifying agent. Four compounds as a formation formateion decene-1 and nitrobenzene hydrogenation at hydrogen atmospheric pressure and 45°C.
In the result of reduction Pt4+ is converted to Pt metal and graphite oxide loses of oxygen. The symbasis
Pt loading with C/O ratio is observed. Compositions Pt - reduced graphite oxide catalyze the hudrogenation of decene-1 and nitrobenzene in a solution. The greatest activity is shown composition reduced by sodium borohydride with the particle size of 2.0 nm, however it is substantially lower than it for Pt/fullerene
black catalyst. Some inhibiton of hydrogenation by incompletely reduced graphite oxide is shown.
 
Publisher Sumy State University
 
Date 2014-05-27T05:39:19Z
2014-05-27T05:39:19Z
2012
 
Type Article
 
Identifier Platinum Nanoparticles Supported on Reduced Graphite Oxide as Hydrogenation Catalyst [Текст] / S.D. Kushch, N.S. Kuyunko, V.E. Muradyan et al. // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V.1, No1. - 01NDLCN06
http://essuir.sumdu.edu.ua/handle/123456789/35054
 
Language en