Synthesis of Ni/NiO Nanosize Powders with Different Phase Ratio by Thermal Decomposition of Nickel Acetate Amines
Electronic Archive of Sumy State University
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Synthesis of Ni/NiO Nanosize Powders with Different Phase Ratio by Thermal Decomposition of Nickel Acetate Amines
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| Creator |
Dulina, I.O.
Lobunets, T.F. Klochkov, L.O. Ragulya, A.V. |
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| Subject |
Nickel Ammine Complexes
Nanopowders IR-Spectroscopy XRD Analysis TG DTA DTG Slit Pore Structure |
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| Description |
Ni/NiO nanopowders with different phase ratio have been prepared using thermal decomposition of nickel acetate ammine complexes containing various ammonia content in air at the temperature range 300 – 500 °C. Obtained powders have been characterized by IR-spectroscopy, XRD and TG, DTA, DTG, TEM, laser granulometry and adsorption-structural method. Thermal decomposition of nickel ammine complexes occurred with forming nickel hydroxide, carbonate and hydroxocarbonate ammines precursors. Composition of the precursors depended on temperature and ammonia content in initial complex. Mean crystallite size of nickel depended on temperature only. In the temperature range from 350 to 500 °C the crystallite size of nickel has grown from 50 to 55 nm. Mean crystallite size of nickel oxide depended on temperature and ammonia content. In the temperature range from 350 to 500 °C the crystallite size of NiO has grown from 5 to 25 nm. Increasing ammonia content from 3.6 to 14.4 mol/mol Ni led to decreasing NiO crystallite size from 8 – 10 to 5 nm. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35125 |
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| Publisher |
Sumy State University
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| Date |
2014-05-27T10:43:03Z
2014-05-27T10:43:03Z 2013 |
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| Type |
Article
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| Identifier |
Synthesis of Ni/NiO Nanosize Powders with Different Phase Ratio by Thermal Decomposition of Nickel Acetate Amines [Текст] / I.O. Dulina, T.F. Lobunets, L.O. Klochkov, A.V. Ragulya
// Nanomaterials: Applications & Properties (NAP-2013) : 3-rd International conference, Alushta, the Crimea, Ukraine, September 16-21, 2013 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2013. - V.2, No2. - 02PCN08
http://essuir.sumdu.edu.ua/handle/123456789/35125 |
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| Language |
en
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