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Fluorescent Few-Atom Clusters of Silver Formed in Organic Solvents on Polymeric Supports

Electronic Archive of Sumy State University

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Title Fluorescent Few-Atom Clusters of Silver Formed in Organic Solvents on Polymeric Supports
 
Creator Kanyuk, M.
Demchenko, A.P.
Díez, I.
Ras, R.H.A.
 
Subject Fluorescence
Probes
Sensing
Imaging
Silver few-atom clusters
Polymeric scaffolds
 
Description Few-atom silver clusters are fluorophores with a set of attractive properties including sub-nanometer
size, high quantum yield and large Stokes shift. Sharing high photostability with semiconductor quantum
dots but being of much smaller size, lacking blinking and with expected lack of toxicity, they are especially
attractive for biological imaging, down to single molecules. No less promising are their applications in
chemical sensing and biosensing as well as for molecular optic and electronic devices on a single molecular
level. We demonstrate that it is not a unique property of water that can provide the formation and stability
of silver clusters. They can be produced on photoreduction in different organic solvents using the same polymeric
template. Unique photophysical properties of these clusters share both similarities and differences
to that of organic dyes.
 
Publisher Sumy State University
 
Date 2014-05-27T10:42:14Z
2014-05-27T10:42:14Z
2012
 
Type Article
 
Identifier Fluorescent Few-Atom Clusters of Silver Formed in Organic Solvents on Polymeric Supports / M. Kanyuk, A. P. Demchenko, I. Díez, R. H. Ras // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No3. - 03CNN18
http://essuir.sumdu.edu.ua/handle/123456789/35122
 
Language en