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Emulsion-Liquid-Membrane Extraction of Alkali Metals by Nano-baskets

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Title Emulsion-Liquid-Membrane Extraction of Alkali Metals by Nano-baskets
 
Creator Mokhtari, B.
Pourabdollah, K.
 
Subject Nano-baskets
Calixcrown
Emulsion Liquid Membrane
Alkali Metals
 
Description Nano-assisted inclusion separation of alkali metals from basic solutions was reported by inclusionfacilitated
emulsion liquid membrane process. The novelty of this study is application of nano-baskets of
calixcrown in the selective and efficient separation of alkali metals as both the carrier and the surfactant.
For this aim, four derivatives of diacid calix[4]-1,3-crowns-4,5 were synthesized, and their inclusionextraction
parameters were optimized including the calixcrown scaffold (4, 4 wt%) as the carrier/
demulsifier, the commercial kerosene as diluent in membrane, sulphonic acid (0.2 M) and ammonium
carbonate (0.4 M) as the strip and the feed phases, the phase and the treat ratios of 0.8 and 0.3, mixing
speed (300 rpm), and initial solute concentration (100 mg/L). The results reveled that under the optimized
operating condition, the degree of inclusion-extraction of alkali metals was as high as 98-99%.
 
Publisher Sumy State University
 
Date 2014-05-27T10:46:43Z
2014-05-27T10:46:43Z
2012
 
Type Article
 
Identifier Mokhtari, B. Emulsion-Liquid-Membrane Extraction of Alkali Metals by Nano-baskets / B. Mokhtari, K. Pourabdollah // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No3. - 03PCSI02
http://essuir.sumdu.edu.ua/handle/123456789/35137
 
Language en