Equilibrium Behavior for Transition Metal Ionic Species in Liquid Phase Deposition Reaction
Electronic Archive of Sumy State University
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Equilibrium Behavior for Transition Metal Ionic Species in Liquid Phase Deposition Reaction
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| Creator |
Mizuhata, Minoru
Ikuta, Hirotaka Okumura, Yuzo Maki, Hideshi |
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| Subject |
Liquid Phase Deposition
Titanium Oxide Chromium Oxide Transition Metal Oxide |
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| Description |
We tried to clarify to the deposition mechanism by applying the 11B and 19F NMR analyses to the LPD reaction solutions for the preparing titanium oxide films with various reaction conditions. Moreover, the optimum conditions of the syntheses of 3d transition metal oxide thin films were investigated by con-trolling pH and the concentration of reacting species. In the reaction of TiO2 deposition, TiF62- do not re-lease all F- ions, namely, the existence of hydrolysis intermediate species (TiFx(OH)y(H2O)6-x-y(4-x-y)) which could not be detected by 19F NMR because of the rapid ligand exchange in the LPD reaction solu-tions. In the reaction of Cr2O3 deposition, the optimization of the LPD reaction can be carried out by the controlling of the concentrations of reaction species and pH.
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| Publisher |
Sumy State University
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| Date |
2014-05-28T06:38:52Z
2014-05-28T06:38:52Z 2013 |
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| Type |
Article
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| Identifier |
Equilibrium Behavior for Transition Metal Ionic Species in Liquid Phase Deposition Reaction [Текст] / M. Mizuhata, H. Ikuta, Y. Okumura, H. Maki
// Nanomaterials: Applications & Properties (NAP-2013) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2013. - V.2, No1. - 01NTF36
http://essuir.sumdu.edu.ua/handle/123456789/35228 |
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| Language |
en
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