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Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase

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Title Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase
 
Creator Sehin, M.Ya.
Tkachuk, A.I.
 
Subject Degree of intercalation
Anatase
Laser irradiation
Specific capacitance
 
Description It is modified matrix of anatase in turn of the thermal and laser treatments. The dependence of Gibbs
energy change of the intercalation reaction of lithium with the guest load degree change was analyzed. Laser
irradiation turned out to increase twice the value of maximum lithium “guest” loading, constricting
heterophase area and changing contrarily concentration genesis of temperature dependence of entropy of
lithium dilution.
The optimal conditions of laser irradiation nanodispersive anatase (pulse energy E 0,02 J, pulse duration
τ 15 ns repetition frequency f 28 Hz, duration of exposure to 5 min.), at which specific energy
characteristics of LPS, formed on its basis, increased by 55% is set.
 
Publisher Sumy State University
 
Date 2014-05-28T07:00:17Z
2014-05-28T07:00:17Z
2012
 
Type Article
 
Identifier Sehin, M.Ya. Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase / M. Y. Sehin, A. I. Tkachuk // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No4. - 04NEA02
http://essuir.sumdu.edu.ua/handle/123456789/35243
 
Language en