Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase
Electronic Archive of Sumy State University
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Title |
Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase
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Creator |
Sehin, M.Ya.
Tkachuk, A.I. |
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Subject |
Degree of intercalation
Anatase Laser irradiation Specific capacitance |
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Description |
It is modified matrix of anatase in turn of the thermal and laser treatments. The dependence of Gibbs energy change of the intercalation reaction of lithium with the guest load degree change was analyzed. Laser irradiation turned out to increase twice the value of maximum lithium “guest” loading, constricting heterophase area and changing contrarily concentration genesis of temperature dependence of entropy of lithium dilution. The optimal conditions of laser irradiation nanodispersive anatase (pulse energy E 0,02 J, pulse duration τ 15 ns repetition frequency f 28 Hz, duration of exposure to 5 min.), at which specific energy characteristics of LPS, formed on its basis, increased by 55% is set. |
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Publisher |
Sumy State University
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Date |
2014-05-28T07:00:17Z
2014-05-28T07:00:17Z 2012 |
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Type |
Article
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Identifier |
Sehin, M.Ya.
Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase / M. Y. Sehin, A. I. Tkachuk
// Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No4. - 04NEA02
http://essuir.sumdu.edu.ua/handle/123456789/35243 |
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Language |
en
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