Запис Детальніше

Excited State Relaxation in Vacuum Deposited and Solution Processed Films of Merocyanine/Fulerene Blends

Electronic Archive of Sumy State University

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Title Excited State Relaxation in Vacuum Deposited and Solution Processed Films of Merocyanine/Fulerene Blends
 
Creator Peckus, D.
Devizis, A.
Hertel, D.
Gulbinas, V.
 
Subject Merocyanine
Heterojunction
Exciton dynamics
Electron donor
Electron acceptor
Organic solar cells
 
Description Exciton dynamics in merocyanine/fulerene blend films made by vacuum deposition and solution processing
techniques were investigated by means of steady-state and time resolved fluorescence and
absorption spectroscopy. Intermolecular charge transfer states are formed during several ps in neat
merocianine films, which determine their fluorescence properties. Fullerene additives cause formation of
new heterogeneous charge transfer states. Even a small fullerene concentration significantly influences
the exciton dynamics by quenching inherent merocianine fluorescent states and causing appearance of new
fluorescence bands caused by the charge transfer states between merocyanine and fullerene molecules. All
fluorescence bands are quenched in films with high fulerence concentration due to the charge carrier generation,
and the quenching effect is stronger in vacuum deposited films.
 
Publisher Sumy State University
 
Date 2014-05-28T10:59:41Z
2014-05-28T10:59:41Z
2012
 
Type Article
 
Identifier Excited State Relaxation in Vacuum Deposited and Solution Processed Films of Merocyanine/Fulerene Blends / D. Peckus, A. Devizis, D. Hertel, V. Gulbinas // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No4. - 04NEA10
http://essuir.sumdu.edu.ua/handle/123456789/35299
 
Language en