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Effects of Deuterium Implantation Dose on Hardness and Deuterium Desorption Temperature Range from High Entropy TiVZrNbHf and TiVZrNbHfN Coatings

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Title Effects of Deuterium Implantation Dose on Hardness and Deuterium Desorption Temperature Range from High Entropy TiVZrNbHf and TiVZrNbHfN Coatings
 
Creator Kuprin, A.S.
Morozov, O.M.
Belous, V.A.
Firstov, S.A.
Gorban, V.F.
Ovcharenko, V.D.
Reshetnyak, E.N.
Tolmachova, G.N.
Zhurba, V.I.
Progolaieva, V.O.
 
Subject High-entropy composites
Deuterium
Hardness
Thermal desorption spectroscopy (TDS)
Implantation
 
Description High entropy TiVZrNbHf and TiVZrNbHfN coatings prepared by filtered vacuum arc plasma from a single
equiatomic HEA cathode. Similarly were obtained titanium and titanium nitride coatings. The structure
of coatings was investigated by X-ray analysis and the changes in nanohardness by nanoindentation method.
The effusion of the implanted deuterium was studied by thermal desorption spectroscopy (TDS).
It is shown that the structure of effusion spectrum is a function of deuterium dose. With increasing implantation
dose deuterium desorption temperature range from coatings is expanding in the direction of
lowering the temperature and the temperature of the peak maximum gas emission gradually shifts to lower
temperatures. For nitride coatings deuterium desorption starts at about room temperature and the maximum
rate of desorption at a temperature of ~500 K.
When irradiation doses more than 5×1017 D/cm2 hardness of nitride coatings decreased by half. Hardness
reduction of coatings is caused by occurrence hydride structural formations in coatings.
 
Publisher Sumy State University
 
Date 2014-05-29T07:05:22Z
2014-05-29T07:05:22Z
2013
 
Type Article
 
Identifier Effects of Deuterium Implantation Dose on Hardness and Deuterium Desorption Temperature Range from High Entropy TiVZrNbHf and TiVZrNbHfN Coatings [Текст] / A.S. Kuprin, O.M. Morozov, V.A. Belous et al. // Nanomaterials: Applications & Properties (NAP-2013) : 3-rd International conference, Alushta, the Crimea, Ukraine, September 16-21, 2013 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2013. - V.2, No2. - 02FNC20
http://essuir.sumdu.edu.ua/handle/123456789/35363
 
Language en