Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems
Electronic Archive of Sumy State University
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems
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| Creator |
Loukova, G.V.
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| Subject |
Photoluminescence
Electron-Exchange Energy Transfer Phosphorescence in Fluids Organo-metallic Clusters Titanium Zirconium Hafnium d0 Metallocenes |
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| Description |
The present contribution will provide an up-to-date overview of novel experimental and theoretical (de-rived quantum-chemically) knowledge on photonics of group IV metallocene-based systems, also with re-spect to their prominent use in catalysis and photoluminescent sensor activity. We have developed photo-physical approach to study measurable properties of the frontier MOs of the complexes, estimate orbital nature of rare long-lived ligand-to-metal charge transfer (LMCT) excited states and also supramolecular interactions between basic components of catalytic systems for polymerization: d0-metal complexes and un-saturated hydrocarbon substrates in fluid systems. In the similar way, the photophysical approach is high-lighted to enable studying fine intermolecular interactions in homogeneous systems with low (catalytic) concentrations of metal complexes that cannot be achieved by other conventional methods.
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| Publisher |
Sumy State University
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| Date |
2014-05-29T08:18:36Z
2014-05-29T08:18:36Z 2013 |
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| Type |
Article
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| Identifier |
Loukova, G.V.
Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems [Текст] / G.V. Loukova
// Nanomaterials: Applications & Properties (NAP-2013) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2013. - V.2, No4. - 04NAESP19
http://essuir.sumdu.edu.ua/handle/123456789/35397 |
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| Language |
en
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