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Formation of J-aggregates of Thiamonomethincyanine Dyes in the Presence of CdTe Nanoparticles

Electronic Archive of Sumy State University

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Title Formation of J-aggregates of Thiamonomethincyanine Dyes in the Presence of CdTe Nanoparticles
 
Creator Dimitriev, O.
Petrenko, V.
Slominski, Yu.
Mazarchyk, I.
 
Subject J-aggregates
Nanocrystals of CdTe
Composite Films
Hybrid Aggregates
Monomers
Dimers
 
Description The conditions of formation of J-aggregates for three types of thiamonomethincyanine dyes, whose
structure is differed by end groups, are studied depending on their concentration and type of interaction
with CdTe nanoparticles with size of about 3 nm in aqueous dispersions. The influence of dye structure on
the efficiency of formation of J-aggregates in solutions and in films was found. It was found that quantum
dots (QDs) of CdTe stabilized by thioglycolic acid can adsorb J-aggregates of the dye molecules on their
surface. It was shown for the first time that the hybrid structure of dye-CdTe can be formed through the
interaction of negatively charged dye molecules and negatively charged surface of the QDs through the
formation of neutral aggregates. It was not found any processes of energy transfer from dye to the particles
of CdTe neither for the dimer - CdTe system nor for the J-aggregates – CdTe system.
 
Publisher Sumy State University
 
Date 2014-05-29T11:34:17Z
2014-05-29T11:34:17Z
2012
 
Type Article
 
Identifier Formation of J-aggregates of Thiamonomethincyanine Dyes in the Presence of CdTe Nanoparticles / O. Dimitriev, V. Petrenko, Y. Slominski, I. Mazarchyk // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No4. - 04FCNF06
http://essuir.sumdu.edu.ua/handle/123456789/35442
 
Language en