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New Materials Based on Carbon-Metal Nanocomposites for Supercapacitor Application

Electronic Archive of Sumy State University

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Title New Materials Based on Carbon-Metal Nanocomposites for Supercapacitor Application
 
Creator Suleimanov, S.M.
Khantimerov, S.M.
Faizrahmanov, I.A.
Abdullin, D.
Togulev, P.N.
 
Subject Carbon Nanotubes
Nanoparticles
Pseudo-capacitance
Supercapacitors
 
Description In this report the approach is developed where the carbon nanotube – metallic nanoparticles composites are used as material of electrodes for electrochemical capacitors based on the double electric layer and pseudo-capacitance effect. To improve the pseudo-capacitance properties the ethanol as the auxiliary reagent is added to the electrolyte to enhance the redox reaction. As active electrode material the two types of carbon-metal composites: carbon nanotube – Ni nanoparticle composites (CNT–Ni) and carbon-palladium hybride films were prepared and studied. The peak on the potentiodynamic curve for CNT–Ni composite electrode in alkaline solutions of ethanol is observed which is ascribed to the ethanol oxidation in alkaline medium. The results obtained are discussed from the point of view both the double layer capacitance and the pseudo capacitance. The carbon-palladium hybride films were prepared by ion evaporation of integrate targets consisting of graphite and metallic palladium. Electron microscopy meas-urements showed that the nanoparticles of palladium were formed in graphite matrix with average dimen-sion of about 3 nm. The contribution of Pd nanoparticles to the electrochemical processes going on the sur-face of the films is considered from the point of view of their electrochemical properties .
 
Publisher Sumy State University
 
Date 2014-05-30T07:12:32Z
2014-05-30T07:12:32Z
2013
 
Type Article
 
Identifier New Materials Based on Carbon-Metal Nanocomposites for Supercapacitor Application [Текст] / S.M. Suleimanov, S.M. Khantimerov, I.A. Faizrahmanov et al. // Nanomaterials: Applications & Properties (NAP-2013) : 3-nd International conference, Alushta, the Crimea, September 16-21, 2013 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2013. - V.2, No4. - 04NEA08
http://essuir.sumdu.edu.ua/handle/123456789/35509
 
Language en