Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3
Vernadsky National Library of Ukraine
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| Title |
Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3
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| Creator |
Ковтун, Г.А.
Пустарнакова, Г.Ф. |
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| Description |
The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated.
The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated. The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated. |
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| Date |
2009-07-14T13:13:14Z
2009-07-14T13:13:14Z 2001 |
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| Type |
Article
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| Identifier |
Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3 / Г.А. Ковтун, Г.Ф. Пустарнакова // Катализ и нефтехимия. — 2001. — № 8. — С. 23-25. — Бібліогр.: 6 назв. — рос.
http://dspace.nbuv.gov.ua/handle/123456789/4046 547.113: 541.124 |
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| Language |
ru
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| Publisher |
Інститут бiоорганiчної хiмiї та нафтохiмiї НАН України
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