Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
Vernadsky National Library of Ukraine
Переглянути архів ІнформаціяПоле | Співвідношення | |
Title |
Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
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Creator |
Korionov, I.V.
Trefilova, A.N. Babushkin, A.N. Korionova, I.G. Shumina, U.N. Lojkowski, W. Opalinska, A. |
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Description |
We present the results of the research work devoted to the problem: how the crystallites influence the electrical properties of stabilized zirconia at pressures of 22−50 GPa and in the temperature range of 77−450 K. The measurements were conducted in the highpressure chamber under direct current on nanocrystalline powders of ZrO₂ stabilized by Pr (0.5%) and on compact powder samples of «partially stabilized» ZrO₂ including 5% Y₃P₃. The nanocrystallite size equals 10, 12 and 56 nm. The change of electronic properties of stabilized zirconia at 31.5–37.5 GPa, 40–44 GPa and 45.5–48.5 GPa in nano- and polycrystalline states has been discovered. It gives us a possibility to verify the phase diagram of ZrO₂ at those intervals of pressure. Besides, it has been revealed that stabilization as nanocrystallinity leads to appearance of additional mechanisms of conductivity in ZrO₂.
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Date |
2014-11-02T08:21:44Z
2014-11-02T08:21:44Z 2007 |
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Type |
Article
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Identifier |
Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure / I.V. Korionov, A.N. Trefilova, A.N. Babushkin, I.G. Korionova, U.N. Shumina, W. Lojkowski, A. Opalinska // Физика и техника высоких давлений. — 2007. — Т. 17, № 1. — С. 70-73. — Бібліогр.: 3 назв. — англ.
0868-5924 PACS: 71.30.+h, 72.20.−i, 73.63.Bd http://dspace.nbuv.gov.ua/handle/123456789/70292 |
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Language |
en
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Relation |
Физика и техника высоких давлений
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Publisher |
Донецький фізико-технічний інститут ім. О.О. Галкіна НАН України
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