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Influence of semiconductor and metal nanoparticles on the dielectric properties of ionic matrix cadmium octanoate

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Title Influence of semiconductor and metal nanoparticles on the dielectric properties of ionic matrix cadmium octanoate
Вплив напівпровідникових та металевих наночастинок на діелектричні властивості іонної матриці октаноата кадмію
 
Creator Zhulai, Dmytro
Fedorenko, Denys
Kovalchuk, Alexander
Bugaychuk, Svetlana
Klimusheva, Gertruda
Mirnaya, Tetyana
 
Subject Ionic liquid crystal
Nanocomposite
Dielectric conductivity
CdS
Au quantum dots
 
Description Dielectric properties of ionic composites consisted of cadmium octanoate matrix and semiconductor or metal
nanoparticles have been investigated. The nanoparticles of different nature (semiconductor CdS, metal Au, and
metal core-semiconductor shell Au-CdS) were chemically synthesized in the smectic A phase of (Cd+2(C7H15COO)−2,
CdC8) that was used as a nanoreactor. These nanocomposites are very stable and well ordered; the size and shape
of the nanoparticles (NPs) are well controlled during the synthesis. The main aim of the research was to examine
the influence of nanoparticles on the dielectric properties of ionic matrix, which has smectic A ordered structure.
Electrical characteristics were investigated at different temperatures, which correspond to different phases of the
material. The conductivity of nanocomposites has an activation nature. The electrical conductivity anisotropy
confirms the structural anisotropy of the nanocomposites. The conductivity of the nanocomposite along the
cation-anion layers is higher by 2 orders of magnitude than that across the cation-anion layers. Basing on the
experimental data, we proposed the simple model of the charge carriage process.
 
Date 2015-12-08T11:54:50Z
2015-12-08T11:54:50Z
2015-01-02
 
Type Article
 
Identifier Kovalchuk A. Influence of semiconductor and metal nanoparticles on the dielectric properties of ionic matrix cadmium octanoate / Dmytro Zhulai, Denys Fedorenko, Alexander Kovalchuk, Svetlana Bugaychuk, Gertruda Vasylivna Klimusheva and Tetyana Alfredivna Mirnaya // Nanoscale Research Letters.- 2015.- .-10:66, pp. 1-6
http://er.knutd.com.ua/handle/123456789/238
 
Language en_US