Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton
Vernadsky National Library of Ukraine
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton
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| Creator |
Byrne, O.
Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
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| Subject |
Nanostructures and Impurity Centers in Cryogenic Environment
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| Description |
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site.
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| Date |
2017-05-19T09:11:28Z
2017-05-19T09:11:28Z 2010 |
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| Type |
Article
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| Identifier |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ.
0132-6414 PACS: 31.70.Dk, 78.40.–q, 78.55.–m http://dspace.nbuv.gov.ua/handle/123456789/117042 |
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| Language |
en
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| Relation |
Физика низких температур
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| Publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
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