The effect of proton ordering in thermal conductivity of clathrate tetrahydrofuran hydrate
Vernadsky National Library of Ukraine
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
The effect of proton ordering in thermal conductivity of clathrate tetrahydrofuran hydrate
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| Creator |
Krivchikov, A.I.
Romantsova, O.O. Korolyuk, O.A. |
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| Subject |
Низкоразмерные и неупорядоченные системы
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| Description |
The effect of proton ordering in tetrahydrofuran hydrate has been detected using a technique based on measurement of thermal conductivity. The thermal conductivity of tetrahydrofuran hydrate was measured by the steady-state potentiometric method in an interval of 2–150 K. Two regimes were selected to observe the effect: (i) slow cooling of the hydrate sample and (ii) doping the hydrate with a small quantity of KOH alkali to a concentration of 10⁻⁴. Proton ordering affects the temperature dependence of the thermal conductivity changing its glass-like behavior to crystal-like below 150 K. The phonon maximum that appears in the temperature dependence of the thermal conductivity at T = 17 K is attributed to the cooperative process of local proton ordering stimulated by orientational and ionic defects. |
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| Date |
2017-05-23T10:20:10Z
2017-05-23T10:20:10Z 2008 |
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| Type |
Article
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| Identifier |
The effect of proton ordering in thermal conductivity
of clathrate tetrahydrofuran hydrate
/ A.I. Krivchikov, O.O. Romantsova, O.A. Korolyuk // Физика низких температур. — 2008. — Т. 34, № 8. — С. 821–828. — Бібліогр.: 54 назв. — англ.
0132-6414 PACS 66.70.–f;63.20.–e;63.20.Pw;63.50.–x http://dspace.nbuv.gov.ua/handle/123456789/117396 |
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| Language |
en
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| Relation |
Физика низких температур
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| Publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
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