Запис Детальніше

IR spectroscopy of KBr salt and crystals

Vernadsky National Library of Ukraine

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Title IR spectroscopy of KBr salt and crystals
 
Creator Goriletsky, V.I.
Mitichkin, A.I.
Belenko, L.E.
Rebrova, T.P.
 
Description The IR absorption spectra of the KBr salt pellets of different purity and crystals grown of them were investigated in the region of 400…4000 cm⁻¹. It was found that by the IR spectra of the KBr salt pellets suitable for growing optically pure crystals one can evaluate the KBr salt quality. Revealed in the IR spectra are not only the impurity oxygen-containing molecular anions and the adsorption water but also, indirectly through them, the most dominating cations of sodium, barium and calcium. Determined was the concentration, beginning from which sodium ions are observed in the IR spectra of the KBr salt pellets. The coefficient of proportionality between the concentration of sulfates in the KBr salt and the absorption coefficient of SO₄²⁻ ions at the frequency of deformation vibration n₄ was found. The latter allows to estimate quantitatively the sulfates in the KBr salt.
 
Date 2017-06-05T17:00:17Z
2017-06-05T17:00:17Z
2001
 
Type Article
 
Identifier IR spectroscopy of KBr salt and crystals / V.I. Goriletsky, A.I. Mitichkin, L.E. Belenko, T.P. Rebrova // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2001. — Т. 4, № 2. — С. 139-141. — Бібліогр.: 7 назв. — англ.
1560-8034
PACS: 78.20.C, 82.80.C, 78.30
http://dspace.nbuv.gov.ua/handle/123456789/119261
 
Language en
 
Relation Semiconductor Physics Quantum Electronics & Optoelectronics
 
Publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України