Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates
Vernadsky National Library of Ukraine
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates
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| Creator |
Smolyak, S.S.
Karbivskyy, V.L. Kasiyanenko, V.H. |
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| Subject |
Modeling and simulation
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| Description |
Effects of partial substitution of Zn by Mn on the electronic and atomic structure of diphosphates Zn₂₋xMnxP₂O₇⋅5H₂O (x = 0.0, 0.7) have been studied out by X-ray photoelectron spectroscopy, IR spectroscopy, NMR and thermogravimetric analysis. Analysis of the infrared absorption spectra was carried out for functional groups of Zn₂P₂O₇⋅5H₂O and Zn₁.₃Mn₀.₇P₂O₇5H₂O compounds. Through correlation between the symmetric and asymmetric stretching vibrations of P-O-P bridge and P-O-P angle an increase of P-O-P bridge angle was established for Zn₁.₃Mn₀.₇P₂O₇5H₂O. Substitution of zinc by manganese has little impact on the overall balance of chemical bond in the compound, which is manifested in minor changes of the core electrons binding energies.
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| Date |
2017-06-12T06:32:30Z
2017-06-12T06:32:30Z 2014 |
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| Type |
Article
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| Identifier |
Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates / S.S. Smolyak, V.L. Karbivskyy, V.H. Kasiyanenko // Functional Materials. — 2014. — Т. 21, № 1. — С. 80-85. — Бібліогр.: 13 назв. — англ.
1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/120372 DOI: dx.doi.org/10.15407/fm21.01.080 |
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| Language |
en
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| Relation |
Functional Materials
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| Publisher |
НТК «Інститут монокристалів» НАН України
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