On features of deoxidization of CsI melt with zirconium getter
Vernadsky National Library of Ukraine
Переглянути архів ІнформаціяПоле | Співвідношення | |
Title |
On features of deoxidization of CsI melt with zirconium getter
|
|
Creator |
Datsko, Yu.N.
Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. |
|
Subject |
Technology
|
|
Description |
Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the deoxidization process very favorable. Practically the interaction leads to decrease of O²⁻ concentration by a factor of ca. 6. Interaction of Zr with carbonate ions is shown both by the calculations and by experiment Ґй lead to the formation of carbon particles (suspension) in the melts that causes certain limitations of the getter treatment for the purification of practically used growth iodide melts.
|
|
Date |
2017-06-12T14:32:50Z
2017-06-12T14:32:50Z 2016 |
|
Type |
Article
|
|
Identifier |
On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ.
1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/120638 DOI: dx.doi.org/10.15407/fm23.02.307 |
|
Language |
en
|
|
Relation |
Functional Materials
|
|
Publisher |
НТК «Інститут монокристалів» НАН України
|
|