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Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases

Vernadsky National Library of Ukraine

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Title Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
 
Creator Konstantinov, V.A.
Manzhelii, V.G.
Revyakin, V.P.
Sagan, V.V.
 
Subject Cryocrystals
 
Description The isochoric thermal conductivities of solid (CO₂)₀,₉₀₅Kr₀,₀₉₅ and (CO2)₁₋xXex(x = 0.052 and
0.097) solution of different densities was investigated in the temperature interval from 150 K to
the onset of melting. An unusual effect of point defects on the thermal conductivity has been detected.
In pure CO₂ at T >150 K the isochoric thermal conductivity decreases smoothly with increasing
temperature. In contrast, the thermal conductivity of solid CO₂/Kr and CO₂/Xe solutions
first decreases passing through a minimum at 200–210 K and then starts to increase with
temperature up to the onset of melting. This behavior of the isochoric thermal conductivity is attributed
to the rotation of the CO₂ molecules which gains more freedom as the spherically symmetrical
inert gas atoms dissolve in CO₂.
 
Date 2017-06-13T09:10:04Z
2017-06-13T09:10:04Z
2006
 
Type Article
 
Identifier Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases / V.A. Konstantinov, V.G. Manzhelii, V.P. Revyakin, V.V. Sagan // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1414–1416. — Бібліогр.: 9 назв. — англ.
0132-6414
PACS: 66.70.+f, 63.20.Ls
http://dspace.nbuv.gov.ua/handle/123456789/120890
 
Language en
 
Relation Физика низких температур
 
Publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України