Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
Vernadsky National Library of Ukraine
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
|
|
| Creator |
Ignatovych, M.
Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. |
|
| Subject |
Surface chemistry of silica and related sorbents
|
|
| Description |
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed.
|
|
| Date |
2017-11-20T18:40:40Z
2017-11-20T18:40:40Z 2002 |
|
| Type |
Article
|
|
| Identifier |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ.
XXXX-0106 http://dspace.nbuv.gov.ua/handle/123456789/126358 |
|
| Language |
en
|
|
| Relation |
Поверхность
|
|
| Publisher |
Інститут хімії поверхні ім. О.О. Чуйка НАН України
|
|