Influence of vibrational anharmonicity and vacancies on thermodynamic properties of the rare gas crystals
Vernadsky National Library of Ukraine
Переглянути архів ІнформаціяПоле | Співвідношення | |
Title |
Influence of vibrational anharmonicity and vacancies on thermodynamic properties of the rare gas crystals
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Creator |
Karasevskii, A.I.
Holzapfel, W.B. |
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Subject |
High-Pressure Studies
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Description |
A statistical method is used to calculate thermodynamic properties of Ar, Kr and Xe (isobaric and isochoric heat capacity, bulk modulus, thermal expansion coefficient, interatomic distances, Grüneisen parameter), and good agreement with experimental values is observed. It is shown that at high temperature, slightly above the melting point of the rare gas crystals, an instability of the crystalline state occurs. As temperature approaches this instability the isobaric heat capacity and the thermal expansion coefficient show strong increases similar to the experimentally observed anomalies.
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Date |
2018-01-14T12:52:00Z
2018-01-14T12:52:00Z 2003 |
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Type |
Article
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Identifier |
Influence of vibrational anharmonicity and vacancies on thermodynamic properties of the rare gas crystals / A.I. Karasevskii, W.B. Holzapfel // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 951-956. — Бібліогр.: 15 назв. — англ.
0132-6414 PACS: 63.70.+h, 64.30.+t, 05.70.Ce http://dspace.nbuv.gov.ua/handle/123456789/128914 |
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Language |
en
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Relation |
Физика низких температур
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Publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
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