Electronic structure peculiarities of disordered Mn and Co diphosphates
Vernadsky National Library of Ukraine
Переглянути архів Інформація| Поле | Співвідношення | |
| Title |
Electronic structure peculiarities of disordered Mn and Co diphosphates
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| Creator |
Karbivskyy, V.L.
Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
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| Subject |
Characterization and properties
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| Description |
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band.
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| Date |
2018-06-15T06:12:18Z
2018-06-15T06:12:18Z 2012 |
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| Type |
Article
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| Identifier |
Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ.
1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/135380 |
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| Language |
en
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| Relation |
Functional Materials
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| Publisher |
НТК «Інститут монокристалів» НАН України
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