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Synthesis of methanol from methane in cavitation field

Електронний науковий архів Науково-технічної бібліотеки Національного університету "Львівська політехніка"

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Title Synthesis of methanol from methane in cavitation field
Синтез метанолу з метану в кавітаційному полі
 
Creator Tselishchev, Oleksii
Ijagbuji, Ayodeji
Loriia, Maryna
Nosach, Vanadii
 
Contributor Volodymyr Dahl East Ukrainian National University
JSC «ORGCHIM»
 
Subject активація метану
гідроксильний радикал
метильний радикал
кавітація
синтез метанолу
methane activation
hydroxyl radical
methyl radical
cavitation
methanol synthesis
 
Description Розроблений спосіб синтезу метанолу за
вільно-радикальним механізмом з використанням метану і
гідроксильних радикалів. Метан та пероксид гідрогену
подаються у кавітаційне поле. Головними продуктами реакції є
метанол і вода. Розраховано ступінь перетворення метану,
який дорівнює ~10 %.
Methanol synthesis was achieved by a
free-radical mechanism of the compounding reaction of
methane and hydroxyl radical. Experiments were
performed by feeding methane and hydrogen-peroxide
into a cavitation field. The major reaction products were
methanol and water molecules. The calculated degree of
methane conversion equals to ~10 %.
 
Date 2019-01-29T12:53:35Z
2019-01-29T12:53:35Z
2018-01-20
2018-01-20
 
Type Article
 
Identifier Synthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73.
http://ena.lp.edu.ua:8080/handle/ntb/43915
Synthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73.
 
Language en
 
Relation Chemistry & Chemical Technology, 1 (12), 2-18
https://doi.org/10.1038/30934
https://doi.org/10.1021/cr00036a005
https://doi.org/10.1070/RC2005v074n12ABEH001199
https://doi.org/10.4028/www.scientific.net/AMR.660.51
https://doi.org/10.1016/j.jece.2014.08.008
https://doi.org/10.1016/j.jhazmat.2009.03.122
https://doi.org/10.1007/978-1-4615-4787-7
https://doi.org/10.1023/A:1015207214720
[1] Imperial Chemical Industries (ICI). Methanol Synthesis Technology, London 1966.
[2] Dlugokencky E., Masarie K., Lang P. et al.: Nature, 1998, 393,447. https://doi.org/10.1038/30934
[3] Crabtree R.: Chem. Rev., 1995, 95, 987.https://doi.org/10.1021/cr00036a005
[4] Rozovskyy A., Lin G.: Teoreticheskie Osnovy Processa Sinteza Metanola. Khimiya, Moskva 1990.
[5] Shilov A., Shul'pin G.: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence ofMetal Complexes [in:] Parkins A. (Ed.), Applied Organometallic Chemistry. Kluwer Academic Publishers, Dordrecht 2000.
[6] Rudakov E.: Elektroliz v Neorganicheskoi Khimii. Naukova Dumka, Kiev 1985.
[7] Arutyunov V., Krylov E.: Uspekhi Khimii, 2005, 74, 1216.https://doi.org/10.1070/RC2005v074n12ABEH001199
[8] Tselishchev A., Zakharov I., Loriya M. et al.: Voprosy Khim. i Khim. Technol., 2012, 2, 39.
[9] Loriya M., Ijagbuji A., Tselischev A. et al.: Adv. Mat. Res., 2013,660, 51. https://doi.org/10.4028/www.scientific.net/AMR.660.51
[10] Tselishchev A., LòriyaM., Zakharov I.: Visnyk Kiev Polytech. Inst., 2011, 65, 111.
[11] Zakharov I., Ijagbuji A., Tselischev A. et al.: J. Environ. Chem. Eng., 2015, 3, 405. https://doi.org/10.1016/j.jece.2014.08.008
[12] ZamilovM., Godin S.: Quant. Potent. Corp., 2012, 1.
[13] Wang X., Wang J., GuoW. et al.: J. Hazard. Mater, 2009, 169,486 – 491. https://doi.org/10.1016/j.jhazmat.2009.03.122
[14] Shah Y., Pandit A., Moholkar V.: Cavitation Reaction Engineering. Kluwer Academic/Plenum Publ., New York 1999.https://doi.org/10.1007/978-1-4615-4787-7
[15] Tselischev A., Nosach V., KoshovetsM. et al.: Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016.
[16] Tselishchev A., Zakharov I., Loriya M. et al.: Khim. Promysh. Ukrainy, 2014, 121, 39.
[17] Tselischev A., Nosach V., KoshovetsM. et. al.: Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016.
[18] Jiang H., Gong H., Yang Z. et al.: React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720
[19] Tselishchev A., LòriyaM., Eliseev P. et al.: East. Eur. J. Enterp. Technol., 2015, 6, 48.
[20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011.
[1] Imperial Chemical Industries (ICI). Methanol Synthesis Technology, London 1966.
[2] Dlugokencky E., Masarie K., Lang P. et al., Nature, 1998, 393,447. https://doi.org/10.1038/30934
[3] Crabtree R., Chem. Rev., 1995, 95, 987.https://doi.org/10.1021/cr00036a005
[4] Rozovskyy A., Lin G., Teoreticheskie Osnovy Processa Sinteza Metanola. Khimiya, Moskva 1990.
[5] Shilov A., Shul'pin G., Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence ofMetal Complexes [in:] Parkins A. (Ed.), Applied Organometallic Chemistry. Kluwer Academic Publishers, Dordrecht 2000.
[6] Rudakov E., Elektroliz v Neorganicheskoi Khimii. Naukova Dumka, Kiev 1985.
[7] Arutyunov V., Krylov E., Uspekhi Khimii, 2005, 74, 1216.https://doi.org/10.1070/RC2005v074n12ABEH001199
[8] Tselishchev A., Zakharov I., Loriya M. et al., Voprosy Khim. i Khim. Technol., 2012, 2, 39.
[9] Loriya M., Ijagbuji A., Tselischev A. et al., Adv. Mat. Res., 2013,660, 51. https://doi.org/10.4028/www.scientific.net/AMR.660.51
[10] Tselishchev A., LòriyaM., Zakharov I., Visnyk Kiev Polytech. Inst., 2011, 65, 111.
[11] Zakharov I., Ijagbuji A., Tselischev A. et al., J. Environ. Chem. Eng., 2015, 3, 405. https://doi.org/10.1016/j.jece.2014.08.008
[12] ZamilovM., Godin S., Quant. Potent. Corp., 2012, 1.
[13] Wang X., Wang J., GuoW. et al., J. Hazard. Mater, 2009, 169,486 – 491. https://doi.org/10.1016/j.jhazmat.2009.03.122
[14] Shah Y., Pandit A., Moholkar V., Cavitation Reaction Engineering. Kluwer Academic/Plenum Publ., New York 1999.https://doi.org/10.1007/978-1-4615-4787-7
[15] Tselischev A., Nosach V., KoshovetsM. et al., Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016.
[16] Tselishchev A., Zakharov I., Loriya M. et al., Khim. Promysh. Ukrainy, 2014, 121, 39.
[17] Tselischev A., Nosach V., KoshovetsM. et. al., Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016.
[18] Jiang H., Gong H., Yang Z. et al., React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720
[19] Tselishchev A., LòriyaM., Eliseev P. et al., East. Eur. J. Enterp. Technol., 2015, 6, 48.
[20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011.
 
Rights © Національний університет „Львівська політехніка“, 2018
© Tselishchev O., Ijagbuji A., Loriia M., Nosach V., 2018
 
Format 69-73
5
application/pdf
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Coverage Lviv
 
Publisher Lviv Politechnic Publishing House